• Agrochemical Pesticide Insecticide Fipronil CAS 120068-37-3
  • Agrochemical Pesticide Insecticide Fipronil CAS 120068-37-3
  • Agrochemical Pesticide Insecticide Fipronil CAS 120068-37-3
  • Agrochemical Pesticide Insecticide Fipronil CAS 120068-37-3

Agrochemical Pesticide Insecticide Fipronil CAS 120068-37-3

CAS No.: 120068-37-3
Formula: C12h4cl2f6n4OS
EINECS: 424-610-5
Appearance: Powder
Source: Organic Synthesis
Toxicity of High and Low: Low Toxicity of Reagents
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Basic Info.

Model NO.
SV112
Mode
Systemic Insecticide
Toxicological Effect
Nerve Poison
Transport Package
25kg/Drum or Customized
Specification
95% TC; 5% WDG, 10% EC
Trademark
SINOVID
Origin
China
HS Code
2903470000
Production Capacity
10000kg/Month

Product Description

Fipronil Basic information
Product Name: Fipronil
Synonyms: 4-((trifluoromethyl)sulfinyl)-;m&b46030;PRINCE;REGENT;FIPRONIL;5-Amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile;FIPRONIL <)>97 % (HPLC, EFF.);Goliath gel
CAS: 120068-37-3
MF: C12H4Cl2F6N4OS
MW: 437.15
EINECS: 424-610-5
Product Categories: Pesticides intermediate;Fipronil insecticidal spectrum is wide, and existing insecticide resistance without interaction;Pesticide intermediates;NULL;MYCODECYL;Agro-Products;Heterocycles;PHARMACEUTICALS;Baby Food Directives 13/2003 EC&14/2003 ECPesticides&Metabolites;AcaricidesMethod Specific;Alpha sort;E-GAlphabetic;European Community: ISO and DIN;F;FA - FLPesticides;Insecticides;Pesticides;Pesticides&Metabolites;Pyrazoles;Ectoparasiticide;API;INSECTICIDE
Mol File: 120068-37-3.mol
 
 
Fipronil Chemical Properties
Melting point  200-201°C
Boiling point  510.1±50.0 °C(Predicted)
density  1.477-1.626
vapor pressure  3.7×10-7 Pa (25 °C)
storage temp.  0-6°C
Water Solubility  1.9-2.4 mg 1l-1 (20 °C)
form  neat
pka -5.86±0.20(Predicted)
λmax 208nm(H2O)(lit.)
Merck  14,4085
BRN  8090115
CAS DataBase Reference 120068-37-3(CAS DataBase Reference)
EPA Substance Registry System Fipronil (120068-37-3)
 
Safety Information
Hazard Codes  T,N
Risk Statements  23/24/25-48/25-50/53-55-57-36
Safety Statements  26-36/37/39-45-60-61-36/37-28
RIDADR  2588
WGK Germany  3
RTECS  UQ4430250
HazardClass  6.1(b)
PackingGroup  III
HS Code  29331990
Hazardous Substances Data 120068-37-3(Hazardous Substances Data)
Toxicity LD50 in rats (mg/kg): 100 orally; >2000 dermally (Colliot); in mice (mg/kg): 32 i.p. (Cole)
 
MSDS Information
Provider Language
5-Amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile English
 
Fipronil Usage And Synthesis
Description Fipronil is a white powder with a mouldy odour. It has a low solubility in water and is a slow-acting poison. It does not bind strongly with soil, and the half-life of fipronil- sulphone is 34 days. Fipronil is a broadspectrum insecticide of the phenylpyrazole group. Fipronil was first used extensively for the control of ants, beetles, cockroaches, fleas; ticks, termites, mole crickets, thrips, rootworms, weevils, flea of pets, field pest of corn, golf courses, and commercial turf, and other insects. Fipronil was first used in the United States in 1996. Fipronil is a topical insecticide. It kills adult fleas and larvae, ticks, and chewing lice. As a liquid, fipronil is applied on the back side skin of dogs and cats. Reports indicate that some animals do become hypersensitive (allergic) to fipronil.
Chemical Properties White crystalline solid.
Chemical Properties White SOlid
Uses antifungal
Uses Pesticide.
Uses A broad spectrum insecticide which actively disrupts the CNS of contacted insects by blocking the passage of chloride ions through GABA receptors.
Uses Fipronil is used for the control of a wide range of insect species in rice, cereals, corn, cotton, top fruit, sugar beet, sugar cane, oilseed rape, many vegetables and other high-value crops. It also has a veterinary use as an ectoparasiticide.
Agricultural Uses Insecticide, Veterinary medicine: Not approved for use in EU countries. Fipronil was introduced into the U.S. in 1996 for use in animal health and indoor pest control. It is the constituent of many products for controlling a wide spectrum of domestic animal and residential pests.
Trade name BES® 602; CEASEFIRE®; CHIPCO®; COMBAT®; FRONTLINE; MB-46030®; H&G®; ICON®; MAXFORCE® ANT STATION; MAXFORCE® ROACH STATION; REGENCY SOFION®; REGENT®; REGENT® 500-FS; TERMIDOR® L VI-NIL
Pharmacology Fipronil is a phenylpyrazole, the mode of action of which is to inhibit nerve transmission in arthropods by blocking γ -aminobutyric acid-gated chloride channels. Fipronil is available as spray and spot-on formulations to control fleas and ticks on cats and dogs. The adulticidal activity of fipronil accounts for the majority of its activity, although additional activity against flea eggs and larvae results from the presence of fipronil on hairs and debris shed into the environment from treated pets.
Autohistoradiography studies (11) into the cutaneous distribution of 14C-fipronil in the cat and dog following spot-on administration demonstrated that radioactivity was restricted principally to the stratum corneum, the viable epidermis, and the pilosebaceous units. Following its slow release from sebaceous glands, fipronil migrates in the sebum covering the skin and hairs by passive diffusion and was shown to persist on hair for up to 2 months after treatment.
Potential Exposure Pyrazole/phenylpyrazole/organofluor ine insecticide; veterinary medicine. Fipronil was intro duced into the United States in 1996 for use in animal health and indoor pest control. It is the constituent of many products for controlling a wide spectrum of domestic ani mal and residential pests. Banned for use in EU.
Metabolic pathway Through the abiotic degradation of fipronil in aqueous solution and on the soil surface, 5-amino-3- carbamoyl-1-[2,6-dichloro-4-(trifluoromethyl)-phenyl]-4- [(trifluoromethyl)sulfinyl]pyrazole is the only hydrolysis product detected. Fipronil in acidic aqueous solution exposed under a xenon lamp degrades with the concomitant appearance of 5-amino-3-cyano-1-[2,6- dichloro-4-(trifluoromethyl)-phenyl]-4- (trifluoromethyl)pyrazole and 5-amino-3-cyano-1-[2,6- dichloro-4-(trifluoromethyl)phenyl]pyrazole-4-sulfonic acid. Under field conditions, when fipronil is applied in formulation, four metabolites which include one product resulting from reduction on the sulfur atom of fipronil are detected.
Shipping UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2902 Pesticide, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
Degradation Fipronil is stable in water at pH 5 and 7 but is slowly hydrolysed at pH 9 (DT50 28 days) to the amide (2). It undergoes rapid aqueous photolysis with a DT50 of <0.5 day. The major photodecomposition product in water and on soil surfaces is desulfinyl-fipronil(3) which is formed by extrusion of the SO group. A minor photoproduct in water, on soil and on plant surfaces is the sulfonic acid (4). The mechanisms of these reactions are discussed in a recent paper by Bobe et al. (1998).
Toxicity evaluation Acute oral LD50 for rats: 100 mg/kg
Waste Disposal It is the responsibility of chemical waste generators to determine the toxicity and physical properties and of a discarded chemical and to properly identify its classification and certification as a haz ardous waste and to determine the disposal method. United States Environmental Protection Agency guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult and fol low all regional, national, state and local hazardous waste laws to ensure complete and accurate classification and dis posal methods.

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Registered Capital
1000000 RMB
Plant Area
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