Agrochemical Pesticide Insecticide Pymetrozine CAS 123312-89-0

• CAS No.: 123312-89-0
• Formula: C10h11n5o
• EINECS: 200-258-5
• Appearance: Granules
• Source: Organic Synthesis
• Toxicity of High and Low: Low Toxicity of Reagents
• Model NO.: SV048
• Mode: Systemic Insecticide
• Toxicological Effect: Nerve Poison
• Transport Package: 25kg/Drum
• Specification: 95%TC, 50%WDG
• Trademark: SINOVID
• Origin: China
• HS Code: 3808929029
• Production Capacity: 50000kg/Month

Product Description

Common Name

Pymetrozine

IUPAC

(E)-4,5-dihydro-6-methyl-4-(3-pyridylmethyleneamino)-1,2,4-triazin-3(2H)-one

 

CAS

4,5-dihydro-6-methyl-4-[(E)-(3-pyridinylmethylene)amino]-1,2,4-triazin-3(2H)-one

 

CAS No.

123312-89-0

 

Molecular Formula

C₁₀H₁₁N₅O

 

General Product Information

 

Category

Insecticides > Insect Antifeedants

 

Activity

Insecticide.Pymetrozine is a systemic insecticide active against motile forms of Hemiptera, including those with MACE and esterase resistance. It has no knockdown activity but crops are protected immediately because feeding ceases soon after ingestion; this is attributed to the product disabling the pests stylet. The insects die of starvation within a few days. The product is plant-systemic. It is readily taken up by leaves and roots and translocated around the plant; it exhibits excellent translaminar activity.  Pymetrozine has also demonstrated a reduction of TYLCV transmission by B tabacii (ie reduced vectoring capability) following foliar applications of pymetrozine to tomatoes. Further studies demonstrated that pymetrozine persists in crops for up to 14 days and should offer protection against the transmission of PLRV (potato leaf roll virus).

Use of a penetrative spray additive is recommended with all applications of Fulfill. The product is rainfast as soon as it has dried.

A minimum of 7 days is required between applications of pymetrozine with a period of 14 days before harvest. Use of the formulations Endeavor and Fulfill would be restricted to no more than two applications per crop at 20 g ai/hl and 96.5 g ai/ha, respectively. The use of the formulation Chess for use on protected pepper, tomato and aubergine is restricted to no more than three per crop and the latest time of application is three days before harvest.

Tests at Rothamsted Research found that aphids showing Modified AcetylCholinEsterase (MACE) resistance survived the winter weather. MACE- resistant aphids are immune to dimethyl carbamates primicarb and triazamate. Other organophosphates and carbamates are still effective. Plenum should be a major part of aphid control programmes if growers suspect MACE resistance. There is no known resistance to Plenum with this aphid. Early action will prevent resistant colonies taking hold in the crop and help ensure subsequent applications prove effective at controlling this and other aphids. Spray programmes should give good penetration of crop canopies and cover as much of the undersides of leaves as possible.

 

CropUse

CropUses: 
alfalfa, asparagus, aubergines, beans, brassicas, chillies, citrus, cole crops, corm vegetables, cotton, cucurbit vegetables, fruits, fruiting vegetables, hops, leafy vegetables, lettuces, mangoes, ornamentals, peaches, pears, pecans, peppers, potatoes, rice, stonefruits, tobacco, tomatoes, tuberous vegetables 
 

Rice	100-200 g ai/ha (foliar application); 1.5 g ai/seedling box
Fruit	10-20 g ai/hl
Vegetables	10-30 g ai/hl
Cotton	100-200 g ai/ha
Hops	5-10 g ai/hl
Ornamentals	10-30 g ai/hl
Pecans	140 g ai/ha (maximum rate)
Potatoes	96.5 g ai/ha

 

Premix

Pymetrozine+isoprocarb
Nitenpyram+Pymetrozine
 
Pymetrozine+Chlorpyrifos
Spirotetramat+Pymetrozine
Pymetrozine+Dinotefuran
Pymetrozine+Lambda-cyhalothrin

 

 

Physical & Safety Data

 

 

Physical Properties

Molecular weight:217.2; Physical form:Colourless crystals. Density:1.36 (20 °C); Melting point:217 °C; Vapour pressure:<4 ×10-3 mPa (25 °C) ( OECD 104); Henry constant:<3.0 ×10-6 Pa m3 mol-1 ( calc.); Partition coefficient(n-octanol and water):logP = -0.18 ( OECD 107); Solubility:In water 0.29 g/l (pH 6.5, 25 °C). In ethanol 2.25; Stability:Stable in air ( OECD 113/DTA). Hydrolysis DT50 4.3 h (pH 1), 25 d (pH 5).

 

Toxicology

(Rat): Oral LD₅₀ >5000 mg/kg; Dermal >2000 mg/kg; Inhalation LC₅₀ (4 h) >3.09 mg/l. Slightly irritating to skin, eyes.

 

Environmental Profile

Ecotoxicology: 
Algae: LC₅₀ (72 h) for Scenedesmus subspicatus 47.1 mg/l; LC₅₀ (5 d) for Selenastrum capricornutum 21.7 mg/l.Bees: LD₅₀ (48 h) (oral) >117 µg/bee; (contact) >200 µg/bee.Birds:Acute oral LD₅₀ for bobwhite quail, mallard ducks >2000 mg/kg. LC₅₀ (8 d) for bobwhite quail >5200 ppm.Daphnia: LC₅₀ (48 h) 87 mg/l.Fish: LC₅₀ (96 h) for rainbow trout and common carp >100 mg/l.Worms: LC₅₀ (14 d) for Eisenia foetida 1098 mg/ kg soil.Other beneficial spp.:Harmless to Aleochara bilineata, Poecilus cupreus, Typhlodromus pyri, Orius insidiosus, Aphidius colemani, Aphidius matricariae, Chrysoperla carnea. 

Environmental fate:
 Animals:Quickly and efficiently eliminated (mainly via excreta) and extensively metabolised in all species tested (rats, farm animals), without accumulation in most major animal food products. The metabolic pathways are similar for all species. Pymetrozine is theSoil:In soils, very rapidly and strongly adsorbed, with low mobility and low leaching potential. Soil 50 2-69 d, DT₉₀ 55-288 d. Rapidly degraded in slightly acidic or sunlight-exposed surface water; 50WATER SOLUBILITY: 270 mg/l at 20°C HAZARDS: Fish: LC₅₀ (96 h) >100 mg/kg (rainbow trout, bluegill sunfish, carp). Bird: Oral LD₅₀ >2000 mg/kg (bobwhite quail, mallard duck). Bee: (48 h) Oral LD₅₀ >117 μg/bee

 

Transport Information

Signal Word:CAUTION; Hazard Class:III(Slightly hazardous)